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What are the Molar Extinction Coefficient Units in ASTRA?

Article number: 319086

ENVIRONMENT

Software:

  • ASTRA 6
  • ASTRA 7
  • ASTRA 8
  • ASTRA V

ANSWER

In ASTRA, the extinction coefficient for the UV detector must be entered in mass concentration units. ASTRA versions 6, 7, and 8 use units of mL/(mg·cm), while ASTRA V uses mL/(g·cm). To convert from molar extinction coefficients to the required mass-based units in ASTRA 6/7/8, use the formula:
εmass [mL/(mg·cm)] = εmolar [L/(cm·mol)] / Mw [g/mol].
For ASTRA V, the conversion is:
εmass [mL/(g·cm)] = εmolar [L/(cm·mol)] / Mw [g/mol] × 1000 [1].

ADDITIONAL INFORMATION

ASTRA requires that the extinction coefficient for the UV detector (UV extinction coefficient) is entered in mass concentration units.

Note: ASTRA 6/7/8 and ASTRA V use different units. ASTRA 6/7/8 use mL/(mg*cm) and ASTRA V uses mL/(g*cm)

Conversion from molar extinction coefficients (ASTRA 6/7/8):

εmass [mL/(mg*cm)] = εmolar [L/(cm*mol)] / Mw [g/mol]

Conversion from molar extinction coefficients (ASTRA V):

εmass [mL/(g*cm)] = εmolar [L/(cm*mol)] / Mw [g/mol] * 1000

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